I think his penis must be pointing forwards instead of down. The wee is going under the seat and on to his pants instead of into the bowl.
Try holding it down while he wees.
I remember having wet pants or seeing a puddle on the floor after sitting on the loo for a poop. My mother used to smack me and say I was a naughty boy for having a wee at the same time as a poop. She said I should stand for a wee and sit for a poop.
Frankly, I can't see how wee can go under the seat if he is sitting on the loo correctly with his penis pointing down.
It must go down!
My sons have all sat on and their pants have always been dry after going.